![]() ![]() van Herk 2.1 Mechanism of Free Radical Polymerisation 23 2.2 Rate of Polymerisation and Development of Molecular Mass Distribution 25 2.2.1 Rate of Polymerisation 25 2.2.2 Kinetic Chain Length 26 2.2.3 Chain Length Distribution 27 2.2.4 Temperature and Conversion Effects 30 2.3 Radical Transfer Reactions 31 2.3.1 Radical Transfer Reactions to Low Molecular Mass Species 31 2.3.2 Radical Transfer Reactions to Polymer 32 2.4 Radical Copolymerisation 34 2.4.1 Derivation of the Copolymerisation Equation 34 2.4.2 Types of Copolymers 37 2.4.3 Polymerisation Rates in Copolymerisations 39 2.5 Controlled Radical Polymerisation 41 3 Emulsion Polymerisation 43 A.M. |a Machine generated contents note: List of Contributors xi Abbreviations xiii List of Frequently Used Symbols xvii Introduction to the Second Edition xix Introduction to the First Edition xxi 1 Historic Overview 1 Finn Knut Hansen 1.1 The Early Stages 1 1.2 The Second Half of the Twentieth Century 9 1.2.1 Product Development 9 1.2.2 Kinetic Theory 11 1.2.3 Emulsion Polymerisation in Monomer Droplets 19 1.2.4 Industrial Process Control and Simulation 21 2 Introduction to Radical (Co)Polymerisation 23 A.M. |a Includes bibliographical references and index. With everyday practice can be a further difficult step, so the book emphasises a clear, comprehensive and straightforward discussion to illustrate how the principles relate to practical application.|a Chemistry and technology of emulsion polymerisation In the development of industrial processes, coupling that understanding ![]() By carefully explaining the principles of the reaction,īased on well-designed experimental investigation, this book provides a practical and intuitive approach On understanding and controlling those properties. Properties including polymerisation kinetics and dispersion stability. Its comparative conciseness (coupled with extensive references) makes it an excellent source for learning the key principles”Įxtended coverage of controlled radical polymerisation in latex productionĮmulsion polymerisation is a complex process, governed by the interplay of both chemical and physical “This book will make an excellent graduate level textbook, and a valuable reference book. I would recommend this book toĪnyone beginning a career in industrial polymer chemistry.” “I wish it had been available when I fi rst started using the technique. "synopsis" may belong to another edition of this title. These latest developments are included in the second edition. Controlled radical polymerisation is used in aiding encapsulation of inorganic particles like pigment particles and clay platelets. ![]() The second edition of this book includes a new chapter on morphology of latex particles, a rapidly progressing area where modelling the thermodynamic and kinetic aspects of phase separation and morphology has developed into a mature and powerful tool to predict and control morphology of latex particles.Īnother area that is rapidly progressing is the application of controlled radical polymerisation in emulsion polymerization. By carefully explaining the principles of the reaction, based on well-designed experimental investigation, the book explains how the principles relate to practical application. For those working in industry, coupling theory with everyday practice can be difficult. Chemistry and Technology of Emulsion Polymerisation 2e provides a practical and intuitive explanation of emulsion polymerization, in combination with both conventional and controlled radical polymerization. ![]()
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